Some CA Facts.
We have found that the weakest link in the chain is typically the substrate so strength claims while important aren't an end all and be all determining factor. Ease of use, non yellowing, safer products, glues that allow for techniques which alleviate dust, and other factors make for the "best" glue for any particular situation. We feel strongly that CA glue can take more of a role in guitar building as its strong and now with more flexible types available some new experimentation can be done. Some tidbits below:
1. What is Cyanoacrylate (CA) and how does it work?
Cyanoacrylate is an acrylic resin with an almost instantaneous curing capacity. When CA is introduced to any source of water, it undergoes a process where the CA molecules start linking up into chains and these chains start whipping around to form a durable plastic mesh. The glue thickens and hardens until the thrashing molecule strands can no longer move. CA will adhere to most anything since almost any substrate you may want to glue will at least have trace amounts of water on its surface.
2. What is the shelf life of CA and the best way to keep it fresh?
If properly made and packaged, CA can last two years or more. The bottle that the CA is packaged in is a vital link to the shelf life of CA. Of the many different HDPE resins, there are only a handful that can properly store CA and isolate the liquid inside from the moisture in the air. The cap or closure is also very important to sealing out the water vapors that exist in the air we breathe. A triple seal closure to keep moisture out and the product inside fresh is best.
The handling of the product, once opened, is also very important to the life span of the product. Always keep the cap on when not in use, always keep the nozzle clean from excess glue and contaminants, keep the CA bottle away from accelerators, and store the sealed bottle in a cool dry place. Also, be sure to allow the glue to go back down the nozzle before recapping. This is key to no clogs.
Storing CA in the refrigerator, in an un-opened only container, will keep the product fresh for a long time. Do not freeze CA; 40˚ F is an ideal temperature. Once you first open the bottle, do not put the bottle back into the refrigerator as this will introduce condensation to the inside of the bottle, which will then react with the CA and it will actually start to set up.
3. Why are there different viscosities of CA?
CA comes in different viscosities so it can be used for a variety of applications. Depending on your hand (technique) and how you work, you would be very surprised at how flexible the viscosity can actually be. You just need to go into it with an open mind and not by rote and you can achieve even better builds using less product with better results.
4. What is a Finisher?
CA by its very nature is extremely brittle and cures very hard. While this can often be a very good attribute, there are circumstances where this can be a negative. Take for example cracks or crevices that will move over time such as a guitar ding or dent or even an entire guitar finish for that matter.
Finishers contain specialized market-specific additives to the formula, giving the product the ability to resist age and temperature changes as well as impact. Finishers can be used in areas where CA has been used before but now with increased performance and super clear results as well as in areas CA has not been used before such as to create guitar finishes and repair finish dings and dents.
5. How strong is CA?
CA is extremely strong, with tensile strengths upwards to two tons per square inch not unusual! While CA is not nearly as strong in shear as it is in tensile, most importantly is that a glue joint is only as strong as the substrates being bonded. For example, if you were to bond balsa wood, the balsa wood itself will always break long before the glue joint would fail, no matter what the forces are.
Since strength is really dependent in most cases on the substrate don’t be overly impressed by strength claims. Remember CA Glue can only be as strong as the substrate that is glued. More strength than the substrate can take is simply overkill. i.e., in our business, the substrate is the weakest link - not the glue. Most important is having a purer, safer, fresher, better looking, and are more workable glue, is what counts.
6. Is your CA pure?
Look for CA's that are not industrial remnants or leftovers (as are most current CA products). Look for CA's that actually come out of the reactor at a high 99% + purity level. And watch for carcinogens which are added to many CA's keep them stable. You don’t need that in there for sure.
7. Why does the nozzle on CA bottles always clog and how can I keep them from clogging?
The CA in the tip of the nozzle is reacting with moisture in the small orifice and hardening. Typically once the CA hardens the user will take a pin and stick it down into the nozzle to open it up only to find it clogs up even quicker the next time. What happens is the pin scratches the inside of the nozzle, which allows even more CA to stay in the nozzle causing it to clog up quicker. This process will be repeated several times until the nozzle is no longer able to be used and gets thrown away.
Some companies have claimed to have a clog-free nozzle, which in reality is only a very long nozzle that you keep snipping the clogged end off until there is no nozzle left and still end up throwing it away. Other companies simply sell you extra caps and nozzles so you can replace them after they clog.
Look for an engineered nozzle that not only will not clog but has three different points of seal to assure the product inside is kept fresh and away from moisture. This cap should have a blunt nose, stainless steel pin molded into the cap, which engages into the orifice of the nozzle (not scratching the insides of the bottle) to keep the orifice clean. Inside the tip, a calculated venturie shape, which pulls the CA out of the tip and back into the bottle once the bottle is stood upright. On the very tip of
the nozzle, a tapered seat which engages with a tapered boss in the cap creating compression on the tip of the nozzle keeping the nozzle clean and the product inside fresh.
If the tip is wiped and the cap is replaced each time the user is finished with the product the nozzle will never clog. Also, be sure to allow the glue to go back down the nozzle before recapping. Tapping the bottle a couple of times will help with this. this is very important.
8. What is blooming (or all this white stuff)?
Blooming is the white haze left behind by CA vapors after a glue cures. This is typically caused by a couple of things - excessive adhesive, an inadequate accelerator is used, high humidity in the area, and improper ventilation around the part while the CA cures.
While blooming does not affect the quality of the bond, if blooming cannot be tolerated at all, try using an accelerator product that will not gas or bloom.
While looking at CA's. Look not only for the highest tensile strength available, but for CA's that are market specific, and are not a trickle down from another industry. Make sure your choice of CA adhesives have been thoroughly tested and selected by top luthiers. Lastly, make sure that your adhesives are purer, safer, fresher, better looking, and are more workable glues.
Your CA's should be "surface insensitive". This means they will work on all woods and substrates, while being as strong or stronger than any substrate you will encounter.
A Word about Viscosity, Thin Glues and Their Use
Thin super glue is designed by manufacturers to be used for very close fitting parts, very rapid cure, and for wicking (getting into pores). Thin glues work best for smooth, close fitting parts with little porosity. Most thin glues allow the parts to actually meet and touch preventing a layer of thick glue between the substrates, so that a "glue sandwich" is not created.
The woods used in guitar manufacturing are of very high quality. Because of this, “most" of the tone woods used are not very porous so thin CA glue is employed because it won't totally wick into the wood but will leave some of the glue on the surface for bonding purposes but because its thin it will not leave a gap of glue between substrates like a thick glue would do. This is good, however, other thin glues will “over wick” and not “wet” enough for most applications which can cause overuse simply because these
other thin glues will take a lot more glue to ultimately load the surface to do the exact same job.
Thins that will not only “wick in”, but “wet” better while wicking will enable you to use less and have better results!!
Look for a CA and Accelerator that will not foam, whiten, bubble, haze, yellow, or pit at all - so that you are left with clearly superior results every single time!!!
There are products that are even designed for specifically for fixing dings and dents and for creating a phenomenally resilient finish on any guitar. These particular specialty products are great for drop fills and even deep gash repairs as well as full instrument finishing. This type of product will contain proprietary Market - specific additives that add flexibility without brittleness, so environmental changes and time won’t affect your work. They are also super strong, versatile and makes ding and dent repairs as well as a complete instrument finishing easy and a new add on service for repair shops.
I hope this helps you along in your quest for better products and work results.
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Rick Rosenberg
President
http://www.gearupproducts.com